<p>Boiling and hydrogen evolving systems both exhibit N-shaped curves, which include peak points known as critical heat flux (CHF) and critical current density (CCD). Since the CCD represents the maximum manageable current density, it would be a tentative obstacle to improving the hydrogen generation rate using a water electrolysis. However, studies explaining the mechanism of or modeling the critical current density (CCD) are scarcely performed. In contrast, substantial efforts have been made to develop the CHF models in the nuclear engineering field, resulting in well-accepted CHF correlations. Based on the analogous N-shaped curves in the two systems, the present study explores the CCD in hydrodynamic perspectives by adopting CHF models. The critical superficial velocities of gas (bubbles), where CHF or CCD occurs are introduced to compare the bubble generation rate adjacent to the surface. The result shows that the critical superficial velocity in the hydrogen evolving experiment is about 100 times smaller than that predicted by the CHF correlation. It seems that remarkably higher active nucleation site density in the hydrogen evolving system attributes the discrepancy. In a phenomenological standpoint, the critical number of surrounding bubbles limiting the gas generation rate was estimated as six in the hydrogen evolving system with a maximum error of 8.07%, which is similar to estimate of five in the boiling system. It is concluded that the CCD phenomenon is governed by the hydrodynamic behavior of the bubbles adjacent to the surface similar to that of the CHF. This work also insists that the key parameter governs CCD is active nucleation site density, while CHF can be predicted well by physical properties of fluid solely.</p>

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Resemblance and Difference in Hydrodynamic Aspects Between Critical Current Density in Water Electrolysis and Critical Heat Flux in Boiling System

  • Haekyun Park

摘要

Boiling and hydrogen evolving systems both exhibit N-shaped curves, which include peak points known as critical heat flux (CHF) and critical current density (CCD). Since the CCD represents the maximum manageable current density, it would be a tentative obstacle to improving the hydrogen generation rate using a water electrolysis. However, studies explaining the mechanism of or modeling the critical current density (CCD) are scarcely performed. In contrast, substantial efforts have been made to develop the CHF models in the nuclear engineering field, resulting in well-accepted CHF correlations. Based on the analogous N-shaped curves in the two systems, the present study explores the CCD in hydrodynamic perspectives by adopting CHF models. The critical superficial velocities of gas (bubbles), where CHF or CCD occurs are introduced to compare the bubble generation rate adjacent to the surface. The result shows that the critical superficial velocity in the hydrogen evolving experiment is about 100 times smaller than that predicted by the CHF correlation. It seems that remarkably higher active nucleation site density in the hydrogen evolving system attributes the discrepancy. In a phenomenological standpoint, the critical number of surrounding bubbles limiting the gas generation rate was estimated as six in the hydrogen evolving system with a maximum error of 8.07%, which is similar to estimate of five in the boiling system. It is concluded that the CCD phenomenon is governed by the hydrodynamic behavior of the bubbles adjacent to the surface similar to that of the CHF. This work also insists that the key parameter governs CCD is active nucleation site density, while CHF can be predicted well by physical properties of fluid solely.