In this paper, we consider the coupled elliptic system with critical exponent and logarithmic terms: \(\begin{aligned} {\left\{ \begin{array}{ll} -\Delta u=\lambda _{1}u+ \mu _1|u|^{2p-2}u+\beta |u|^{p-2}|v|^{p}u+\theta _1 u\log u^2, &{} \quad x\in \Omega ,\\ -\Delta v=\lambda _{2}v+ \mu _2|v|^{2p-2}v+\beta |u|^{p}|v|^{p-2}v+\theta _2 v\log v^2, &{}\quad x\in \Omega ,\\ u=v=0, &{}\quad x \in \partial \Omega , \end{array}\right. } \end{aligned}\) where \(\Omega \subset {\mathbb R}^N\) is a bounded smooth domain, \(2p=2^*=\frac{2N}{N-2}\) is the Sobolev critical exponent. When \(N \ge 5\) , for different ranges of \(\beta ,\lambda _{i},\mu _i,\theta _{i}\) , \(i=1,2\) , we obtain existence and nonexistence results of positive solutions via variational methods. The special case \(N=4 \) was studied by Hajaiej et al. (Positive solution for an elliptic system with critical exponent and logarithmic terms, arXiv:2304.13822, 2023). Note that for \(N\ge 5\) , the critical exponent is given by \(2p\in \left( 2,4\right) \) ; whereas for \(N=4\) , it is \(2p=4\) . In the higher-dimensional cases \(N\ge 5\) brings new difficulties, and requires new ideas. Besides, we also study the Brézis–Nirenberg problem with logarithmic perturbation \(\begin{aligned} -\Delta u=\lambda u+\mu |u|^{2p-2}u+\theta u \log u^2 \quad \text { in }\Omega , \end{aligned}\) where \(\mu >0, \theta <0\) , \(\lambda \in {\mathbb R}\) , and obtain the existence of positive local minimum and least energy solution under some certain assumptions.