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<p>Trace amounts of Zr and V can increase the recrystallization temperature of Al-Mg-Si wrought aluminum alloys, which is expected to regulate the recrystallization grain. In this paper, trace amounts of V and Zr were added to recycled Al-Mg-Si alloys, and their effects on the microstructure and mechanical properties of the cast alloys were studied by scanning electron microscopy (SEM) and synchrotron radiation X-ray tomography (SRXT). The results show that the addition of Zr significantly increases the grain sizes due to the “Zr poisoning”; V addition has no significant effect on the grain size. The morphology of Fe-rich phase gradually changes from the large Chinese-script shape to the fine short rod and curved long strip shape, and the distribution uniformity is improved with the combined addition of V and Zr. The three-dimensional (3D) morphology of Fe-rich phase includes granular, short rod-like, simple branch and multi-branch structures. The individual addition of V and Zr has no significant effect on the morphology of Fe-rich phase; but the combined addition of V and Zr significantly increases the number and volume fraction of Fe-rich phase with small size (diameter ≤15 µm), the number of branches in the largest Fe-rich phase is significantly reduced, resulting in the improvement of elongation. This work provides a theoretical basis for the development of new recycled Al-Mg-Si alloys in industrial application.</p>

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Effect of trace Zr and V on 3D morphology of Fe-rich phase and mechanical properties in recycled Al-Mg-Si alloy

  • 期刊论文

  • 发表日期：

    2025年6月1日

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  • Dong-fu Song,
  • Yu-liang Zhao,
  • Yue-hua Cai,
  • Dong-yang Yang,
  • Zheng-chao Xie,
  • Xiang-jie Wang,
  • Wei-wen Zhang

摘要

Trace amounts of Zr and V can increase the recrystallization temperature of Al-Mg-Si wrought aluminum alloys, which is expected to regulate the recrystallization grain. In this paper, trace amounts of V and Zr were added to recycled Al-Mg-Si alloys, and their effects on the microstructure and mechanical properties of the cast alloys were studied by scanning electron microscopy (SEM) and synchrotron radiation X-ray tomography (SRXT). The results show that the addition of Zr significantly increases the grain sizes due to the “Zr poisoning”; V addition has no significant effect on the grain size. The morphology of Fe-rich phase gradually changes from the large Chinese-script shape to the fine short rod and curved long strip shape, and the distribution uniformity is improved with the combined addition of V and Zr. The three-dimensional (3D) morphology of Fe-rich phase includes granular, short rod-like, simple branch and multi-branch structures. The individual addition of V and Zr has no significant effect on the morphology of Fe-rich phase; but the combined addition of V and Zr significantly increases the number and volume fraction of Fe-rich phase with small size (diameter ≤15 µm), the number of branches in the largest Fe-rich phase is significantly reduced, resulting in the improvement of elongation. This work provides a theoretical basis for the development of new recycled Al-Mg-Si alloys in industrial application.