Performance optimization of thermal integrated-Carnot battery for waste heat utilization in industrial integrated energy systems
摘要
Thermally integrated Carnot battery (TI-CB) systems offer unique advantages for industrial waste heat recovery, but their performance under fluctuating, off-design conditions remains poorly understood. To address this gap, this study proposes a quasi-dynamic mathematical model with solution methodologies applicable to both design and off-design operating conditions. A dynamic evaluation framework is also developed to account for the temporal mismatch between energy storage and release processes. A multi-operating-condition set constructed via multivariable sampling is used to enable systematic analysis of key design parameters under both design and off-design conditions. The results reveal that heat source utilization parameters and heat pump temperature rise are dominant factors affecting TI-CB performance, while off-design analysis shows that ORC mass flow rate variations have a more significant impact on system performance than heat pump fluctuations. Due to irreversible heat losses, an increase in the heat source temperature difference leads to a decrease in round-trip efficiency (ηrt) from 62.6% to 45.8%, while ηorc and ηex also exhibit downward trends. A higher temperature lift in the heat pump results a decrease in the mean COP from 7.6 to 4.8, whereas ηorc increases from 7.0% to 10.2%. Among working fluids evaluated, R1336mzz(Z) demonstrates superior performance but exhibits nonlinear behavior, while R1233zd(E) provides optimal stability across operating ranges, making it suitable for practical engineering applications.