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<p>We developed metal–organic framework (MOF) derivatives via rapid thermal processing (RTP) of ZIF-67, achieving synthesis in ∼30 min far faster than conventional pyrolysis. These derivatives retain the morphology of ZIF-67, integrating carbon nanotubes and nickel–cobalt nanoparticles within a porous carbon matrix. With surface areas of ∼ 208–225 m<sup>2</sup>·g<sup>−1</sup>, they excel in styrene epoxidation, yielding 80% conversion and 50%–60% selectivity. This efficient RTP method enhances stability and activity, offering a scalable approach to advance MOF-based catalysis.</p>

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Blazing fast MOF magic: carbon nanotubes derived from MOFs for catalysis

  • 期刊论文

  • 发表日期：

    2025年12月16日

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  • Chuan Xu,
  • Junge Zhang,
  • Jiaxin Liu,
  • Weiqiang Zhou,
  • Xianghai Song,
  • Xin Liu,
  • Yangyang Yang,
  • Qian Yang,
  • Yi Guo,
  • Yuqiao Zhang,
  • Jisheng Zhang,
  • Pengwei Huo,
  • Long Zhang

摘要

We developed metal–organic framework (MOF) derivatives via rapid thermal processing (RTP) of ZIF-67, achieving synthesis in ∼30 min far faster than conventional pyrolysis. These derivatives retain the morphology of ZIF-67, integrating carbon nanotubes and nickel–cobalt nanoparticles within a porous carbon matrix. With surface areas of ∼ 208–225 m2·g−1, they excel in styrene epoxidation, yielding 80% conversion and 50%–60% selectivity. This efficient RTP method enhances stability and activity, offering a scalable approach to advance MOF-based catalysis.