Zeolites for the separation of ethylene, ethane, and ethyne
摘要
The cost-effective separation of ethylene (C2H4), ethyne (C2H2), and ethane (C2H6) poses a significant challenge in the contemporary chemical industry. In contrast to the energy-intensive high-pressure cryogenic distillation process, zeolite-based adsorptive separation offers a low-energy alternative. This review provides a concise overview of recent advancements in the adsorptive separation of C2H4, C2H2, and C2H6 using zeolites or zeolite-based adsorbents. It commences with an examination of the industrial significance of these compounds and the associated separation challenges. Subsequently, it systematically examines the utilization of various types of zeolites with diverse cationic species in such separation processes. And then it explores how different zeolitic structures impact adsorption and separation capabilities, considering principles such as cation-π interaction, π-complexation, and steric separation concerning C2H4, C2H2, and C2H6 molecules. Furthermore, it discusses methods to enhance the separation performance of zeolites and zeolite-based adsorbents, encompassing structural design, modifications, and ion exchange processes. Finally, it summarizes current research trends and future directions, highlighting the potential application value of zeolitic materials in the field of C2H4, C2H2, and C2H6 separation and offering recommendations for further investigation.