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<p>Herein, we report an enantioselective Pd-catalyzed allylic amination reaction using phosphoramidite-selenide ligands. A wide variety of N-nucleophiles are suitable in this reaction, furnishing corresponding allylic amination products in up to 93% yield and 90%&#xa0;ee.</p>

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Palladium/phosphoramidite-selenide-catalyzed enantioselective allylic amination

  • 期刊论文

  • 发表日期：

    2026年2月2日

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  • Bin Feng,
  • Yuan-Cheng Li,
  • Tang-Ling Hou,
  • Cui-Zhen Wang,
  • Hong-Kai Huang,
  • Ge-Yun You

摘要

Herein, we report an enantioselective Pd-catalyzed allylic amination reaction using phosphoramidite-selenide ligands. A wide variety of N-nucleophiles are suitable in this reaction, furnishing corresponding allylic amination products in up to 93% yield and 90% ee.