<p>In this paper, Fe-based composite coatings reinforced by Ni-coated-Al<sub>2</sub>O<sub>3</sub> particles were prepared by laser cladding to investigate the influence of Ni-coated-Al<sub>2</sub>O<sub>3</sub> addition on corrosion and wear resistance. Microstructure and microhardness of Fe-based composite coatings were characterized by using x-ray diffraction, scanning electron microscope and Vickers hardness tester. Corrosion behavior was evaluated using potentiodynamic polarization tests and electrochemical impedance spectroscopy experiments. Wear behavior was conducted by a dry reciprocating sliding wear tester. Results show that Fe-based composite coatings exhibit smooth columnar microstructure and grain refinement induced by the addition of Al<sub>2</sub>O<sub>3</sub> ceramic particles. The microhardness of the Fe-based composite coating is much higher than that of the substrate and increases with the increase in Ni-coated-Al<sub>2</sub>O<sub>3</sub> content. The corrosion current density of Fe-based composite coatings is 5.84 × 10<sup>-4</sup> A·cm<sup>-2</sup> for pure Fe-based coating, 2.37 × 10<sup>-4</sup> A·cm<sup>-2</sup> for 1 wt.% Ni-coated-Al<sub>2</sub>O<sub>3</sub> coating, 2.09 × 10<sup>-4</sup> A·cm<sup>-2</sup> for 3 wt.% Ni-coated-Al<sub>2</sub>O<sub>3</sub> coating and 10.70 × 10<sup>-4</sup> A·cm<sup>-2</sup> for 5 wt.% Ni-coated-Al<sub>2</sub>O<sub>3</sub> coating, respectively. Corrosion resistance can be notably enhanced by appropriate addition of Ni-coated-Al<sub>2</sub>O<sub>3</sub>. Also, wear resistance of Fe-based composite coating has been significantly improved by the addition of Ni-coated-Al<sub>2</sub>O<sub>3</sub>. The Fe-based composite coating with 3 wt.% Ni-coated-Al<sub>2</sub>O<sub>3</sub> displays the highest wear resistance. The wear mechanism of Fe-based composite coatings is a mixture of abrasive wear and adhesive wear as well as oxidation wear mechanisms. The proposed Fe-based composite coatings can be applied to improve the corrosion and wear resistance of components in contact with high-speed fluids, such as hydraulic turbine blades and ship propellers.</p>

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Effect of Ni-Coated-Al2O3 Addition on Corrosion and Wear Resistance of Laser Cladded Fe-Based Composite Coatings

  • Weifeng Xin,
  • Erguang Fu,
  • Fanchang Dai,
  • Xinlong Wei,
  • Chao Zhang

摘要

In this paper, Fe-based composite coatings reinforced by Ni-coated-Al2O3 particles were prepared by laser cladding to investigate the influence of Ni-coated-Al2O3 addition on corrosion and wear resistance. Microstructure and microhardness of Fe-based composite coatings were characterized by using x-ray diffraction, scanning electron microscope and Vickers hardness tester. Corrosion behavior was evaluated using potentiodynamic polarization tests and electrochemical impedance spectroscopy experiments. Wear behavior was conducted by a dry reciprocating sliding wear tester. Results show that Fe-based composite coatings exhibit smooth columnar microstructure and grain refinement induced by the addition of Al2O3 ceramic particles. The microhardness of the Fe-based composite coating is much higher than that of the substrate and increases with the increase in Ni-coated-Al2O3 content. The corrosion current density of Fe-based composite coatings is 5.84 × 10-4 A·cm-2 for pure Fe-based coating, 2.37 × 10-4 A·cm-2 for 1 wt.% Ni-coated-Al2O3 coating, 2.09 × 10-4 A·cm-2 for 3 wt.% Ni-coated-Al2O3 coating and 10.70 × 10-4 A·cm-2 for 5 wt.% Ni-coated-Al2O3 coating, respectively. Corrosion resistance can be notably enhanced by appropriate addition of Ni-coated-Al2O3. Also, wear resistance of Fe-based composite coating has been significantly improved by the addition of Ni-coated-Al2O3. The Fe-based composite coating with 3 wt.% Ni-coated-Al2O3 displays the highest wear resistance. The wear mechanism of Fe-based composite coatings is a mixture of abrasive wear and adhesive wear as well as oxidation wear mechanisms. The proposed Fe-based composite coatings can be applied to improve the corrosion and wear resistance of components in contact with high-speed fluids, such as hydraulic turbine blades and ship propellers.