Fabrication of Low-cost As-cast Ti30Ni35Cu15Zr20 High-Entropy Shape Memory Alloys Via Yttrium Addition and their Property Enhancement
摘要
In this study, a series of (Ti30Ni35Cu15Zr20)100-xYx (x = 0, 0.5, 1, 2, 5) high-entropy shape memory alloys (HESMAs) were fabricated via vacuum arc melting. The effects of rare earth element yttrium (Y) addition on the microstructure, mechanical properties, superelasticity, and stability of the Ti30Ni35Cu15Zr20 alloy were investigated using scanning electron microscopy (SEM), x-ray diffraction (XRD), energy-dispersive x-ray spectroscopy (EDS), and room temperature cyclic compression tests. The results indicate that the addition of Y within a certain composition range significantly improves the properties of the quaternary Ti30Ni35Cu15Zr20 alloy. Specifically, when the Y content is 0.5 at.% and 1 at.%, the mechanical properties of the high-entropy shape memory alloy are notably enhanced, with the alloy containing 1 at.% Y (Y1) exhibiting the optimal mechanical performance. It possesses a maximum recoverable strain of 8.2%, a superelastic strain of 4.3%, a compressive strength of 1892 MPa, and a fracture strain of 16% at room temperature. When the content of Y is 1 at.%, the distribution of precipitated phases in the alloy is relatively uniform, with no obvious local aggregation or sparse regions. The grains are also finer than those of alloys in the same composition group. Among them, the size of the second phase is moderate and its morphology is regular. However, these properties gradually deteriorate when the Y content exceeds 2%. In the cyclic compression tests with a fixed strain of 8%, both the Y0.5 and Y1 alloys achieve a 100% recovery rate after one cycle, and their superelasticity tends to stabilize.
Graphical Abstract