<p>Although considerable efforts have investigated the strengthening effects of carbides on laser-cladded alloy coatings, the effects of different carbide types on coating properties remain insufficiently clarified, and relevant strategies for regulating carbide types via alloying element modification have been rarely reported. In this paper, the effects of in situ synthesized carbide hard phases on the microstructure and properties of laser-cladded AlCoCrFeNi-C high-carbon high-entropy alloy (HC-HEA) coatings were studied. The results demonstrate that designed four HEA coatings exhibit a BCC/B2 matrix with different types of carbides at the grain boundaries. Specifically, the primary carbide formed in both the AlCoCrFeNi-C and AlCoCrFeNiMo<sub>0.2</sub>-C coatings is M<sub>7</sub>C<sub>3</sub>. With the further addition of W, the AlCoCrFeNiMo<sub>0.2</sub>W<sub>0.2</sub>-C coating precipitates M<sub>7</sub>C<sub>3</sub>, M<sub>23</sub>C<sub>6</sub>, and M<sub>6</sub>C multiple types of carbides. By simultaneously reducing the Cr content, the AlCoCr<sub>0.5</sub>FeNiMo<sub>0.2</sub>W<sub>0.2</sub>-C coating achieves a single M<sub>6</sub>C carbide, which is more beneficial to hardness, crack resistance, and high-temperature stability than M<sub>7</sub>C<sub>3</sub> and M<sub>23</sub>C<sub>6</sub>. This coating reaches a maximum hardness of 879.3 ± 10.5 HV<sub>0.5</sub> after aging at 600&#xa0;°C, with no cracks observed at the tips of the microhardness indentation. Meanwhile, the M<sub>6</sub>C carbide remains stable after aging at 800&#xa0;°C. In contrast, the other three coatings undergo carbide transformations: M<sub>7</sub>C<sub>3</sub> → M<sub>23</sub>C<sub>6</sub> and M<sub>23</sub>C<sub>6</sub> → M<sub>6</sub>C. Furthermore, due to the enhanced crack resistance imparted by the discrete single M<sub>6</sub>C phase, the coating exhibits better high-temperature wear performance compared to the other coatings at 600&#xa0;°C. Therefore, this work reveals an effective approach to tailor carbide types in HC-HEA coatings. The superior performance of the AlCoCr<sub>0.5</sub>FeNiMo<sub>0.2</sub>W<sub>0.2</sub>-C coating is attributed to the exclusive formation of M<sub>6</sub>C carbide.</p>

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In Situ Synthesized Carbides-Reinforced AlCoCrFeNi-C High-Carbon High-Entropy Alloy Coatings by Laser Cladding

  • Shiqi Huang,
  • Jingxi Zhang,
  • Yuyun Lu,
  • Dong Hao

摘要

Although considerable efforts have investigated the strengthening effects of carbides on laser-cladded alloy coatings, the effects of different carbide types on coating properties remain insufficiently clarified, and relevant strategies for regulating carbide types via alloying element modification have been rarely reported. In this paper, the effects of in situ synthesized carbide hard phases on the microstructure and properties of laser-cladded AlCoCrFeNi-C high-carbon high-entropy alloy (HC-HEA) coatings were studied. The results demonstrate that designed four HEA coatings exhibit a BCC/B2 matrix with different types of carbides at the grain boundaries. Specifically, the primary carbide formed in both the AlCoCrFeNi-C and AlCoCrFeNiMo0.2-C coatings is M7C3. With the further addition of W, the AlCoCrFeNiMo0.2W0.2-C coating precipitates M7C3, M23C6, and M6C multiple types of carbides. By simultaneously reducing the Cr content, the AlCoCr0.5FeNiMo0.2W0.2-C coating achieves a single M6C carbide, which is more beneficial to hardness, crack resistance, and high-temperature stability than M7C3 and M23C6. This coating reaches a maximum hardness of 879.3 ± 10.5 HV0.5 after aging at 600 °C, with no cracks observed at the tips of the microhardness indentation. Meanwhile, the M6C carbide remains stable after aging at 800 °C. In contrast, the other three coatings undergo carbide transformations: M7C3 → M23C6 and M23C6 → M6C. Furthermore, due to the enhanced crack resistance imparted by the discrete single M6C phase, the coating exhibits better high-temperature wear performance compared to the other coatings at 600 °C. Therefore, this work reveals an effective approach to tailor carbide types in HC-HEA coatings. The superior performance of the AlCoCr0.5FeNiMo0.2W0.2-C coating is attributed to the exclusive formation of M6C carbide.