<p>FeCoNiCr<sub>x</sub> (<i>x</i> = 0, 0.5, 0.6, 0.7, 0.8) high-entropy alloy (HEA) cladding layers were prepared using the plasma cladding method, to study the corrosion resistance of FeCoNiCr<sub>x</sub> high-entropy alloy cladding layers. This article investigates the effect of Cr content on the phase structure, microstructure, and corrosion resistance of FeCoNi-based high-entropy alloys. The results indicate that the FeCoNiCr<sub>x</sub> high-entropy alloy cladding layer prepared by plasma melting is an FCC solid solution with uniform composition and defect-free microstructure. When the Cr content increases, the corrosion resistance of the high-entropy alloy cladding layer exhibits a development pattern that first increases and then decreases. The corrosion morphology changes from uniform corrosion of FeCoNi to localized pitting corrosion of FeCoNiCr<sub>x</sub>. The FeCoNiCr<sub>0.7</sub> coating has the best corrosion resistance, with the lowest corrosion current density (5.702 nA/cm<sup>2</sup>) and the highest breakdown potential (− 0.152 <i>V</i><sub>Ag/AgCl</sub>). The results indicate that there is an optimal critical value for the Cr element in the FeCoNiCr<sub>x</sub> cladding layer. When the Cr content is low, the density of the oxide film is poor due to the lack of Cr<sup>3+</sup>. When the content of Cr exceeds the optimal level, Cr-O-based oxide segregation can lead to uneven composition in the passivation film, thereby disrupting the continuity of the oxide film and reducing corrosion resistance.</p>

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Corrosion Resistance of FeCoNiCrx High-Entropy Alloy Cladding Layer Prepared by Plasma Cladding

  • Zhang Xingye,
  • Xing Bowei,
  • Li Guangquan,
  • Huang Guoxuan,
  • Zuo Xiaojiao,
  • Zhang Xunye,
  • Zhang Nannan

摘要

FeCoNiCrx (x = 0, 0.5, 0.6, 0.7, 0.8) high-entropy alloy (HEA) cladding layers were prepared using the plasma cladding method, to study the corrosion resistance of FeCoNiCrx high-entropy alloy cladding layers. This article investigates the effect of Cr content on the phase structure, microstructure, and corrosion resistance of FeCoNi-based high-entropy alloys. The results indicate that the FeCoNiCrx high-entropy alloy cladding layer prepared by plasma melting is an FCC solid solution with uniform composition and defect-free microstructure. When the Cr content increases, the corrosion resistance of the high-entropy alloy cladding layer exhibits a development pattern that first increases and then decreases. The corrosion morphology changes from uniform corrosion of FeCoNi to localized pitting corrosion of FeCoNiCrx. The FeCoNiCr0.7 coating has the best corrosion resistance, with the lowest corrosion current density (5.702 nA/cm2) and the highest breakdown potential (− 0.152 VAg/AgCl). The results indicate that there is an optimal critical value for the Cr element in the FeCoNiCrx cladding layer. When the Cr content is low, the density of the oxide film is poor due to the lack of Cr3+. When the content of Cr exceeds the optimal level, Cr-O-based oxide segregation can lead to uneven composition in the passivation film, thereby disrupting the continuity of the oxide film and reducing corrosion resistance.