<p>To enhance the wear resistance and reduce friction in hydraulic support columns, thereby extending their service life, the β-Si<sub>3</sub>N<sub>4</sub>/304SS composite coatings were fabricated on the 27SiMn steel substrate via high-speed laser processing. The organization and wear and friction-reduction properties of β-Si<sub>3</sub>N<sub>4</sub>/304SS composite coatings fabricated via high-speed laser cladding (HLC) (the content of β-Si<sub>3</sub>N<sub>4</sub> was 0, 1, 2, 3, 4, and 5 wt.%, respectively) were investigated. The results show that the β-Si<sub>3</sub>N<sub>4</sub>/304SS composite coatings fabricated via laser cladding technology are composed of striped columnar crystals and equiaxed crystals in the middle and upper parts. The middle and lower parts of the coatings near the fusion line are rich in equiaxed crystals and fine dendritic crystals among the striped columnar crystals. The incorporation of β-Si<sub>3</sub>N<sub>4</sub> particles induces the transformation of the lower and middle regions of the coatings into fine equiaxed grains and cellular crystals, and the metal nitrides CrN, and metal silicides CrSi<sub>2</sub> and Fe<sub>2</sub>Si were generated in the coating, which was influenced by the strengthening phase and part of grain refinement compared with that without the β-Si<sub>3</sub>N<sub>4</sub> coating. Grains and cellular crystals, metal nitride CrN, and metal silicides CrSi<sub>2</sub> and Fe<sub>2</sub>Si were produced in the coating. The hardness of 1% ~ 5% β-Si<sub>3</sub>N<sub>4</sub> coatings was increased by 1.07 ~ 1.46 times compared with that of the no-β-Si<sub>3</sub>N<sub>4</sub> coatings due to the influence of reinforced phases and partial grain refinement, and the friction mass loss was reduced from 0.0037 to 0.0011&#xa0;g, which was reduced by 70%. The friction coefficient dropped from 0.7178 to 0.5548, resulting in a 22.71% decrease. β-Si<sub>3</sub>N<sub>4</sub> ceramic granules can significantly improve the hardness and abrasion resistance of 304SS coating.</p>

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Microstructure Regulation and Tribological Response Mechanism of β-Si3N4-Modified 304 Stainless-Steel Coatings

  • Shuisheng Chen,
  • Yang Zhou,
  • Nannan Zhang,
  • Qian Chen,
  • Peicheng Peng,
  • Mohan Deng

摘要

To enhance the wear resistance and reduce friction in hydraulic support columns, thereby extending their service life, the β-Si3N4/304SS composite coatings were fabricated on the 27SiMn steel substrate via high-speed laser processing. The organization and wear and friction-reduction properties of β-Si3N4/304SS composite coatings fabricated via high-speed laser cladding (HLC) (the content of β-Si3N4 was 0, 1, 2, 3, 4, and 5 wt.%, respectively) were investigated. The results show that the β-Si3N4/304SS composite coatings fabricated via laser cladding technology are composed of striped columnar crystals and equiaxed crystals in the middle and upper parts. The middle and lower parts of the coatings near the fusion line are rich in equiaxed crystals and fine dendritic crystals among the striped columnar crystals. The incorporation of β-Si3N4 particles induces the transformation of the lower and middle regions of the coatings into fine equiaxed grains and cellular crystals, and the metal nitrides CrN, and metal silicides CrSi2 and Fe2Si were generated in the coating, which was influenced by the strengthening phase and part of grain refinement compared with that without the β-Si3N4 coating. Grains and cellular crystals, metal nitride CrN, and metal silicides CrSi2 and Fe2Si were produced in the coating. The hardness of 1% ~ 5% β-Si3N4 coatings was increased by 1.07 ~ 1.46 times compared with that of the no-β-Si3N4 coatings due to the influence of reinforced phases and partial grain refinement, and the friction mass loss was reduced from 0.0037 to 0.0011 g, which was reduced by 70%. The friction coefficient dropped from 0.7178 to 0.5548, resulting in a 22.71% decrease. β-Si3N4 ceramic granules can significantly improve the hardness and abrasion resistance of 304SS coating.