<p>The metadynamic recrystallization (MDRX) behavior of Super304H austenitic heat-resistant steel was systematically investigated, and its hot processing parameters were optimized by integrating processing maps with microstructural analysis. Double-pass hot compression tests (temperature: 950-1150&#xa0;°C, strain rate: 0.01-5&#xa0;s<sup>−1</sup>, inter-pass time: 5-30&#xa0;s) were conducted to develop an Avrami-type kinetic equation, which is quantified by: <InlineEquation ID="IEq1"> <EquationSource Format="TEX">\(X_{{{\text{MDRX}}}} = 1 - exp\left[ { - 0.693\left( {t/t_{0.5} } \right)^{0.623} } \right]\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <msub> <mi>X</mi> <mtext>MDRX</mtext> </msub> <mo>=</mo> <mn>1</mn> <mo>-</mo> <mi>e</mi> <mi>x</mi> <mi>p</mi> <mfenced close="]" open="["> <mrow> <mo>-</mo> <mn>0.693</mn> <msup> <mfenced close=")" open="("> <mrow> <mi>t</mi> <mo stretchy="false">/</mo> <msub> <mi>t</mi> <mrow> <mn>0.5</mn> </mrow> </msub> </mrow> </mfenced> <mrow> <mn>0.623</mn> </mrow> </msup> </mrow> </mfenced> </mrow> </math></EquationSource> </InlineEquation>, <InlineEquation ID="IEq2"> <EquationSource Format="TEX">\(t_{0.5} = 3.18 \times 10^{ - 9} \dot{\varepsilon }^{ - 0.264} exp\left( {252330/RT} \right)\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <msub> <mi>t</mi> <mrow> <mn>0.5</mn> </mrow> </msub> <mo>=</mo> <mn>3.18</mn> <mo>×</mo> <msup> <mn>10</mn> <mrow> <mo>-</mo> <mn>9</mn> </mrow> </msup> <msup> <mover accent="true"> <mi>ε</mi> <mo>˙</mo> </mover> <mrow> <mo>-</mo> <mn>0.264</mn> </mrow> </msup> <mi>e</mi> <mi>x</mi> <mi>p</mi> <mfenced close=")" open="("> <mrow> <mn>252330</mn> <mo stretchy="false">/</mo> <mi>R</mi> <mi>T</mi> </mrow> </mfenced> </mrow> </math></EquationSource> </InlineEquation>, where <i>X</i><sub>MDRX</sub> is the MDRX fraction, <i>t</i> is the inter-pass time, <i>t</i><sub>0.5</sub> is the time for 50% recrystallization, <InlineEquation ID="IEq3"> <EquationSource Format="TEX">\(\dot{\varepsilon }\)</EquationSource> <EquationSource Format="MATHML"><math> <mover accent="true"> <mi>ε</mi> <mo>˙</mo> </mover> </math></EquationSource> </InlineEquation> is the strain rate, <i>Q</i> is the activation energy of MDRX, <i>R</i> is the universal gas constant, and <i>T</i> is the deformation temperature. The results demonstrate that MDRX progression exhibits a strong positive correlation with deformation temperature, strain rate, and inter-pass time, and the proposed kinetic equation accurately predicts MDRX behavior. Nano-sized Nb-rich MX-type precipitates hinder grain boundary migration via the Zener pinning effect, leading to a significant increase in MDRX activation energy (<i>Q</i> = 252.3&#xa0;kJ/mol) compared to conventional 304 austenitic steels. The established processing maps reveal that prolonged inter-pass time shifts instability zones from low-temperature/high-strain-rate regions to high-temperature/high-strain-rate regions. By combining microstructural evolution analysis with model predictions, the optimal processing window was identified as 1100-1150&#xa0;°C/0.1-1&#xa0;s<sup>−1</sup>. This study provides a theoretical foundation for optimizing high-temperature forming processes and microstructure control in Nb-microalloyed austenitic steels.</p>

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Decoupling Metadynamic Recrystallization Kinetics and Hot Processing Window Effects in Super304H Austenitic Steel: A Processing-Map Guided Strategy for Multi-Pass Hot Rolling Optimization

  • Long Chen,
  • Hua-yun Du,
  • Li-feng Hou,
  • Qian Wang,
  • Huan Wei,
  • Xiao-da Liu,
  • Yan Zhou,
  • Ying-hui Wei

摘要

The metadynamic recrystallization (MDRX) behavior of Super304H austenitic heat-resistant steel was systematically investigated, and its hot processing parameters were optimized by integrating processing maps with microstructural analysis. Double-pass hot compression tests (temperature: 950-1150 °C, strain rate: 0.01-5 s−1, inter-pass time: 5-30 s) were conducted to develop an Avrami-type kinetic equation, which is quantified by: \(X_{{{\text{MDRX}}}} = 1 - exp\left[ { - 0.693\left( {t/t_{0.5} } \right)^{0.623} } \right]\) X MDRX = 1 - e x p - 0.693 t / t 0.5 0.623 , \(t_{0.5} = 3.18 \times 10^{ - 9} \dot{\varepsilon }^{ - 0.264} exp\left( {252330/RT} \right)\) t 0.5 = 3.18 × 10 - 9 ε ˙ - 0.264 e x p 252330 / R T , where XMDRX is the MDRX fraction, t is the inter-pass time, t0.5 is the time for 50% recrystallization, \(\dot{\varepsilon }\) ε ˙ is the strain rate, Q is the activation energy of MDRX, R is the universal gas constant, and T is the deformation temperature. The results demonstrate that MDRX progression exhibits a strong positive correlation with deformation temperature, strain rate, and inter-pass time, and the proposed kinetic equation accurately predicts MDRX behavior. Nano-sized Nb-rich MX-type precipitates hinder grain boundary migration via the Zener pinning effect, leading to a significant increase in MDRX activation energy (Q = 252.3 kJ/mol) compared to conventional 304 austenitic steels. The established processing maps reveal that prolonged inter-pass time shifts instability zones from low-temperature/high-strain-rate regions to high-temperature/high-strain-rate regions. By combining microstructural evolution analysis with model predictions, the optimal processing window was identified as 1100-1150 °C/0.1-1 s−1. This study provides a theoretical foundation for optimizing high-temperature forming processes and microstructure control in Nb-microalloyed austenitic steels.