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Effects of Trace La on the Aging Properties of the Cu-Ti-Zr Alloys

  • Nengneng Wang,
  • Meng Zhou,
  • Baohong Tian,
  • Jin Zou,
  • Ke Jing,
  • Haoyan Hu,
  • Yi Zhang,
  • Qian Bai,
  • Caijiao Tian,
  • Xu Li,
  • Alex A. Volinsky

摘要

Cu-2Ti-0.3Zr and Cu-2Ti-0.3Zr-0.2La alloys were prepared by vacuum melting, and their mechanical properties and conductivity were measured after aging treatment. Both alloys were aged at 450 °C for 30 min to obtain optimum properties, and the microhardness of the Cu-Ti-Zr-La alloy increased by 8.5% and the strength by 5% compared to the Cu-Ti-Zr alloy. Characterization of the alloys by EBSD revealed that the addition of La inhibits grain growth, refines the grains and enhances the texture. The Cu4Ti phase precipitated during the Cu-Ti-Zr alloy’s aging process, and the Cu5Zr phase precipitated after La was added. It was found by analyzing the strengthening mechanisms of the Cu-Ti-Zr-La alloy that precipitation strengthening significantly contributes to the alloy strength.