Application and Research Progress of Electrochemical Impedance Spectroscopy in State-of-Health Estimation for Lead-Acid Batteries
摘要
In order to prevent safety hazards and economic losses caused by sudden battery failures, accurately assessing the state of health (SOH) of lead-acid batteries is essential. Electrochemical impedance spectroscopy (EIS), a noninvasive and information-rich characterization technology, has proven effective for this purpose. This review focuses on the application of EIS in evaluating lead-acid battery SOH. We first provide a comprehensive overview of primary aging mechanisms and their corresponding impedance signatures. We then systematically analyze conventional methods for extracting SOH information from EIS data, including equivalent circuit models, characteristic frequency selection, distribution of relaxation times (DRT), and machine learning. A comparative approach is employed to evaluate the advantages, limitations, and applicable scenarios of each method. Finally, we discuss key challenges in the online application of EIS and offer perspectives on future development trends. This review synthesizes recent research findings and methodological advances to promote intelligent health management technologies for lead-acid batteries.