<p>The structural and luminescence properties of the apatite-type compound Ca<sub>2</sub>La<sub>3</sub>(SiO<sub>4</sub>)<sub>3</sub>F:Eu<sup>3+</sup> synthesized by solid-state reaction are reported herein. Ca<sub>2</sub>La<sub>3</sub>(SiO<sub>4</sub>)<sub>3</sub>F possesses hexagonal symmetry with space group <InlineEquation ID="IEq1"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="11664_2025_11824_Article_IEq1.gif" Format="GIF" Height="19" Rendition="HTML" Resolution="72" Type="Linedraw" Width="51" /> </InlineMediaObject> <EquationSource Format="TEX">\( P6_{3} /{\text{m}}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mi>P</mi> <msub> <mn>6</mn> <mn>3</mn> </msub> <mo stretchy="false">/</mo> <mtext>m</mtext> </mrow> </math></EquationSource> </InlineEquation>. The surface morphology of the prepared phosphor was confirmed by scanning electron microscopy (SEM), and the chemical composition was confirmed by energy-dispersive x-ray spectroscopy (EDS). The prepared Ca<sub>2</sub>La<sub>3</sub>(SiO<sub>4</sub>)<sub>3</sub>F:Eu<sup>3+</sup> was excited at 392&#xa0;nm, and an intense peak obtained at 615&#xa0;nm was attributed to <sup>5</sup>D<sub>0</sub> → <sup>7</sup>F<sub>2</sub> transition along with other weak emission peaks. Judd–Ofelt intensity parameters for f–f transitions of Eu<sup>3+</sup> were derived from the emission spectra. Orange-red emission was confirmed by the CIE chromatic coordinate diagram. This phosphor is suitable for applications in solid-state lighting, display devices, and other optical applications.</p>

错误:搜索内容不能为空,请输入英文关键词
错误:关键词超出字数限制,请精简
高级检索

Spectroscopic Properties and Judd–Ofelt Analysis of Ca2La3(SiO4)3F:Eu3+ Phosphor

  • Akshay Pimpalkar,
  • Shruti Dhale,
  • Nilesh Ugemuge,
  • Ashok Mistry,
  • Rujuta Barve Joshi,
  • Sarika Khapre,
  • Milind Patwardhan,
  • Kishor Raulkar

摘要

The structural and luminescence properties of the apatite-type compound Ca2La3(SiO4)3F:Eu3+ synthesized by solid-state reaction are reported herein. Ca2La3(SiO4)3F possesses hexagonal symmetry with space group \( P6_{3} /{\text{m}}\) P 6 3 / m . The surface morphology of the prepared phosphor was confirmed by scanning electron microscopy (SEM), and the chemical composition was confirmed by energy-dispersive x-ray spectroscopy (EDS). The prepared Ca2La3(SiO4)3F:Eu3+ was excited at 392 nm, and an intense peak obtained at 615 nm was attributed to 5D0 → 7F2 transition along with other weak emission peaks. Judd–Ofelt intensity parameters for f–f transitions of Eu3+ were derived from the emission spectra. Orange-red emission was confirmed by the CIE chromatic coordinate diagram. This phosphor is suitable for applications in solid-state lighting, display devices, and other optical applications.