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Highly Crystalline and Stoichiometric Growth of CdTe by Cost-Effective Hydrothermal Technique

  • Maruti V. Salve,
  • Aparna S. Ukarande,
  • O. I. Olusola,
  • T. M. W. J. Bandara,
  • M. Furlani,
  • B.-E. Mellander,
  • M. A. K. L. Dissanayake,
  • I. Albinsson,
  • Nandu B. Chaure

摘要

CdTe powder samples have been synthesized using a hydrothermal approach, employing cadmium acetate and tellurium dioxides as sources of Cd and Te, respectively. NaBH4 was utilized as the reducing agent, and double-distilled water was used as the solvent in the synthesis process. The effect of annealing on the synthesized samples was investigated. The samples have been characterized by x-ray powder diffraction, Raman spectroscopy, UV-Vis-NIR spectroscopy, scanning electron microscopy, energy dispersive spectroscopy, and x-ray photoelectron spectroscopy. The electrical properties (current–voltage and capacitance–voltage) of the as-prepared and annealed CdTe pellets were investigated. These findings indicate that annealing can lead to improvements in crystallinity, crystallite size, and electrical conductance. This paper presents a simple, cost-effective, and versatile method for producing significant amounts of CdTe nanostructure powders with properties suitable for use in the fabrication of CdS/CdTe solar cells.