Influence of MnO2 on Quality of High Alumina Iron Ore Pellets
摘要
The quality of iron ore pellets is influenced by iron ore gangue content, flux composition, firing temperature, and time. High alumina levels in iron ore fines adversely affect pellet quality, including cold compressive strength (CCS), reduction degradation index (RDI), tumbler index (TI), and abrasion index (AI). This study investigates the influence of varying iron ore alumina concentrations (2.3, 3.2, and 4.0 pct) on pellet quality. Green pellets were indurated at 1280 °C. Fired pellet properties such as strength, porosity, RDI, and Hoogoven Simulation (HOSIM), a blast furnace reduction behavior simulation test, were studied. To understand the phase and microstructural changes, fired pellets were characterized using XRD, phase quantification, SEM-EDS, and elemental mapping. Results show that pellet strength decreased from 260 to 174 kg/pellet as alumina increased from 2.3 to 4.0 pct. The variation in pellet strength after reduction was also analyzed to assess the pellets’ stability in the blast furnace. FactSage studies were conducted to understand and quantify the evolution of the slag phase. A decrease in melt formation and fewer solid-state crystalline bonds results in lower pellet strength. To improve the quality of high alumina iron ore pellets, MnO2 is added at dosages ranging from 0.5 to 2 pct in increments of 0.5 pct. Detailed MnO2 ore characterization was conducted using chemical analysis, density, XRD, TGA-DSC, and SEM-EDS to understand the thermal stability and interactions with the pellet matrix. The MnO2 addition not only increases the strength of high alumina iron ore pellets by 29.88 pct (from 174 to 226 kg/pellet), but it also reduces the reducibility time by 13 pct (from 158 to 137 minutes) due to the structural integrity of fired pellets.
Graphical abstract