<p>Medium-Mn steels usually require long intercritical annealing to achieve sufficient Mn partitioning and metastable austenite, which compromises energy efficiency and scalability. Here we elucidate a solidification–phase transformation coupling mechanism in a strip-cast 9Mn steel, emphasizing how solidification-preset Mn micro-segregation governs subsequent austenite reverse transformation and lamellar microstructure inheritance. Sub-rapid solidification generates periodic Mn-enriched interdendritic bands (<InlineEquation ID="IEq1"> <EquationSource Format="TEX">\({{k}^{^{\prime}}}_{\text{M}\text{n}}\)</EquationSource> <EquationSource Format="MATHML"><math> <mmultiscripts> <mrow> <mmultiscripts> <mrow> <mi>k</mi> </mrow> <mrow /> <mmultiscripts> <mrow /> <mrow /> <mo>′</mo> </mmultiscripts> </mmultiscripts> </mrow> <mtext>Mn</mtext> <mrow /> </mmultiscripts> </math></EquationSource> </InlineEquation> ≈ 1.45&#xa0;−&#xa0;1.55) and stabilizes a fraction of pre-existing austenite at room temperature, establishing a macroscopically homogeneous yet microscopically heterogeneous chemical–structural template. In-situ high-temperature observations reveal that the inherited Mn heterogeneity markedly accelerates austenite reversion, lowering the transformation onset temperature and increasing nucleation density relative to a homogenized counterpart, thereby producing refined and spatially registered austenite morphologies. During intercritical rolling, the Mn-enriched bands are geometrically elongated and refined; diffusion-length estimates based on lattice diffusion predict negligible Mn redistribution, whereas experiments indicate pronounced Mn re-patterning, implying dominant short-circuit diffusion along deformation-induced defects and phase boundaries. This coupled “template inheritance + fast-channel redistribution” mechanism is summarized schematically and explains the emergence of a refined lamellar γ/α′ heterostructure through a simplified processing route. Tensile results are consistent with the microstructure refinement and retained heterogeneity, demonstrating that exploiting solidification-preset chemical templates provides an energy-efficient pathway for microstructure control in strip-cast medium-Mn steels.</p>

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Solidification-Preset Mn Micro-Segregation Governing Austenite Reverse Transformation in a Strip-Casting Medium-Mn Steel

  • Hui Xu,
  • Yutian Liang,
  • Peisheng Lyu,
  • Ligang Liu,
  • Xuan Chen,
  • Wanlin Wang

摘要

Medium-Mn steels usually require long intercritical annealing to achieve sufficient Mn partitioning and metastable austenite, which compromises energy efficiency and scalability. Here we elucidate a solidification–phase transformation coupling mechanism in a strip-cast 9Mn steel, emphasizing how solidification-preset Mn micro-segregation governs subsequent austenite reverse transformation and lamellar microstructure inheritance. Sub-rapid solidification generates periodic Mn-enriched interdendritic bands ( \({{k}^{^{\prime}}}_{\text{M}\text{n}}\) k Mn ≈ 1.45 − 1.55) and stabilizes a fraction of pre-existing austenite at room temperature, establishing a macroscopically homogeneous yet microscopically heterogeneous chemical–structural template. In-situ high-temperature observations reveal that the inherited Mn heterogeneity markedly accelerates austenite reversion, lowering the transformation onset temperature and increasing nucleation density relative to a homogenized counterpart, thereby producing refined and spatially registered austenite morphologies. During intercritical rolling, the Mn-enriched bands are geometrically elongated and refined; diffusion-length estimates based on lattice diffusion predict negligible Mn redistribution, whereas experiments indicate pronounced Mn re-patterning, implying dominant short-circuit diffusion along deformation-induced defects and phase boundaries. This coupled “template inheritance + fast-channel redistribution” mechanism is summarized schematically and explains the emergence of a refined lamellar γ/α′ heterostructure through a simplified processing route. Tensile results are consistent with the microstructure refinement and retained heterogeneity, demonstrating that exploiting solidification-preset chemical templates provides an energy-efficient pathway for microstructure control in strip-cast medium-Mn steels.