<p>Hydrogen (<InlineEquation ID="IEq1"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="11663_2025_3619_Article_IEq1.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="20" /> </InlineMediaObject> <EquationSource Format="TEX">\({\hbox {H}}_{{2}}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>H</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation>)-based fluidized bed reduction is a promising route for carbon-neutral ironmaking, but defluidization caused by interparticle sticking of <InlineEquation ID="IEq2"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="11663_2025_3619_Article_IEq1.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="20" /> </InlineMediaObject> <EquationSource Format="TEX">\({\hbox {H}}_{{2}}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>H</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation>-Direct Reduced Iron (DRI) remains a major challenge. The present study examines the influence of sticking behavior and flowability on fluidized bed stability during <InlineEquation ID="IEq3"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="11663_2025_3619_Article_IEq1.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="20" /> </InlineMediaObject> <EquationSource Format="TEX">\({\hbox {H}}_{{2}}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>H</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation> reduction. Experiments with hematite- and goethite-based ores revealed distinct fluidization behaviors. The hematite-based ore exhibited defluidization at 750&#xa0;<InlineEquation ID="IEq4"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="11663_2025_3619_Article_IEq4.gif" Format="GIF" Height="7" Rendition="HTML" Resolution="72" Type="Linedraw" Width="9" /> </InlineMediaObject> <EquationSource Format="TEX">\(^{\circ }\)</EquationSource> <EquationSource Format="MATHML"><math> <mmultiscripts> <mrow /> <mrow /> <mo>∘</mo> </mmultiscripts> </math></EquationSource> </InlineEquation>C to 850&#xa0;<InlineEquation ID="IEq5"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="11663_2025_3619_Article_IEq4.gif" Format="GIF" Height="7" Rendition="HTML" Resolution="72" Type="Linedraw" Width="9" /> </InlineMediaObject> <EquationSource Format="TEX">\(^{\circ }\)</EquationSource> <EquationSource Format="MATHML"><math> <mmultiscripts> <mrow /> <mrow /> <mo>∘</mo> </mmultiscripts> </math></EquationSource> </InlineEquation>C due to whisker-induced Fe layer formation, while the hematite-goethite-mixed ore remained stable without whisker formation. Quantitative rheological analysis confirmed that defluidization correlated with a transition from “Easy-Flowing” to “Cohesive” regime when interparticle cohesion exceeded a critical threshold. To prevent the defluidization, ore blending strategies were explored as a mean to satisfy the rheological properties identified in the present study. A 20&#xa0;pct blending of hematite-goethite-mixed ore effectively ensured “Easy-Flowing” regime and lowered the chance of cohesion below the critical value, ensuring stable fluidization. These findings provide key insights into the sticking mechanisms of <InlineEquation ID="IEq6"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="11663_2025_3619_Article_IEq1.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="20" /> </InlineMediaObject> <EquationSource Format="TEX">\({\hbox {H}}_{{2}}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>H</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation>-DRI and highlight the critical powder characteristics necessary to achieve a stable and efficient <InlineEquation ID="IEq7"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="11663_2025_3619_Article_IEq1.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="20" /> </InlineMediaObject> <EquationSource Format="TEX">\({\hbox {H}}_{{2}}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>H</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation> reduction process.</p>

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Effect of Ore Types and Temperature on Sticking and Flowability of Direct Reduced Iron in a Hydrogen Fluidized Bed Reduction

  • Jae-Dong Kim,
  • Tae-Hyeon Kim,
  • Chang-kuk Ko,
  • Young-Seok Lee,
  • Myoung Gyun Shin,
  • Youn-Bae Kang

摘要

Hydrogen ( \({\hbox {H}}_{{2}}\) H 2 )-based fluidized bed reduction is a promising route for carbon-neutral ironmaking, but defluidization caused by interparticle sticking of \({\hbox {H}}_{{2}}\) H 2 -Direct Reduced Iron (DRI) remains a major challenge. The present study examines the influence of sticking behavior and flowability on fluidized bed stability during \({\hbox {H}}_{{2}}\) H 2 reduction. Experiments with hematite- and goethite-based ores revealed distinct fluidization behaviors. The hematite-based ore exhibited defluidization at 750  \(^{\circ }\) C to 850  \(^{\circ }\) C due to whisker-induced Fe layer formation, while the hematite-goethite-mixed ore remained stable without whisker formation. Quantitative rheological analysis confirmed that defluidization correlated with a transition from “Easy-Flowing” to “Cohesive” regime when interparticle cohesion exceeded a critical threshold. To prevent the defluidization, ore blending strategies were explored as a mean to satisfy the rheological properties identified in the present study. A 20 pct blending of hematite-goethite-mixed ore effectively ensured “Easy-Flowing” regime and lowered the chance of cohesion below the critical value, ensuring stable fluidization. These findings provide key insights into the sticking mechanisms of \({\hbox {H}}_{{2}}\) H 2 -DRI and highlight the critical powder characteristics necessary to achieve a stable and efficient \({\hbox {H}}_{{2}}\) H 2 reduction process.