<p>In this study, the holey graphene was prepared by microwave-assisted chemical etching. The three-dimensional (3D) holey graphene hydrogel was obtained through hydrothermal self-assembly method, followed by the introduction of FeCo<sub>2</sub>S<sub>4</sub> particles. The resulting holey graphene hydrogel, characterized by high specific surface area and abundant pores combined with FeCo<sub>2</sub>S<sub>4</sub> with high pseudocapacitance by interfacial interaction, shortened the mass transport path and enhanced the specific capacitance. The findings reveal that the holey graphene hydrogel/FeCo<sub>2</sub>S<sub>4</sub> (FeCo<sub>2</sub>S<sub>4</sub>/HGH) composite exhibits high specific capacitance and impressive rate capability (413.4 F·g<sup>−1</sup> at 1 A·g<sup>−1</sup>, 300.4 F·g<sup>−1</sup> at 6 A·g<sup>−1</sup>). The symmetric supercapacitor operated within a stable potential window of 0.1–1.6 V, achieving specific capacitance of 127.5 F·g<sup>−1</sup> at 1 A·g<sup>−1</sup>, and can deliver 37.1 Wh·kg<sup>−1</sup> at a power density of 1 499 W·kg<sup>−1</sup>. Besides, under the current density of 3 A·g<sup>−1</sup>, the supercapacitor retained 90.8% of its capacitance after 5 000 cycles, demonstrating exceptional cycle stability. This study presents an efficient method for fabricating advanced integrated supercapacitors electrodes with enhanced energy density.</p>

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Synergistic Integration of FeCo2S4 Particles with Holey Graphene Hydrogel for Enhanced Performance Solid-state Supercapacitor

  • Chuang Zhou,
  • Ling Ding,
  • Shiqian Li,
  • Qingtian Zhang,
  • Zhifu Zhao,
  • Qi Wang,
  • Hao Chen,
  • Zhengzai Cheng,
  • Lesly Dasilva Wandji Djouonkep,
  • Guanghua Wang,
  • Wenxin Xiang,
  • Wenbing Li

摘要

In this study, the holey graphene was prepared by microwave-assisted chemical etching. The three-dimensional (3D) holey graphene hydrogel was obtained through hydrothermal self-assembly method, followed by the introduction of FeCo2S4 particles. The resulting holey graphene hydrogel, characterized by high specific surface area and abundant pores combined with FeCo2S4 with high pseudocapacitance by interfacial interaction, shortened the mass transport path and enhanced the specific capacitance. The findings reveal that the holey graphene hydrogel/FeCo2S4 (FeCo2S4/HGH) composite exhibits high specific capacitance and impressive rate capability (413.4 F·g−1 at 1 A·g−1, 300.4 F·g−1 at 6 A·g−1). The symmetric supercapacitor operated within a stable potential window of 0.1–1.6 V, achieving specific capacitance of 127.5 F·g−1 at 1 A·g−1, and can deliver 37.1 Wh·kg−1 at a power density of 1 499 W·kg−1. Besides, under the current density of 3 A·g−1, the supercapacitor retained 90.8% of its capacitance after 5 000 cycles, demonstrating exceptional cycle stability. This study presents an efficient method for fabricating advanced integrated supercapacitors electrodes with enhanced energy density.