Let \(\gamma _2(G)\) and \(\gamma _3(G)\) be the second and the third largest roots of the Laplacian matching polynomial of a simple graph G. In this note we structurally characterize the graphs in the sets \(\mathcal {S}' \subset \mathcal {S}\) , where \(\mathcal {S}= \{ G \mid \gamma _3(G) <2 \}\) and \(\mathcal {S}'= \{ G \mid \gamma _2(G) \geqslant 2, \; \gamma _3(G) <2 \}\) .