<p>Tin dioxide (SnO<sub>2</sub>) has gained wide recognition as a potential candidate for high-capacity anode applications in sodium-ion battery systems due to its great advantages in theoretical capacity and costs. However, its practical application is hindered by several critical challenges, including substantial volume expansion during charge/discharge cycles, low electronic conductivity, and sluggish electrochemical reaction kinetics. In contrast, defect engineering offers a viable solution to these limitations. By strategically modifying crystal structures through oxygen vacancy creation, solid solution modification, and elemental doping, the sodium storage performance of SnO<sub>2</sub> anodes can be substantially improved. This review first provides a concise introduction to the challenges facing SnO<sub>2</sub> anodes and the limitations of conventional modification approaches. Subsequently, it systematically examines various approaches to boost the electrochemical behavior of SnO<sub>2</sub> as an anode material. Finally, the review outlines both the potential challenges and promising prospects of employing defect engineering to enhance the performance of SnO<sub>2</sub> as a high-efficiency anode material for sodium storage.</p>

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Defect engineering in SnO2-based materials toward high-performance anode for sodium storage

  • Zhoule Gu,
  • Zirui Ren,
  • Hongqiao Li,
  • Kangwen He,
  • Xiaoxiao Lu

摘要

Tin dioxide (SnO2) has gained wide recognition as a potential candidate for high-capacity anode applications in sodium-ion battery systems due to its great advantages in theoretical capacity and costs. However, its practical application is hindered by several critical challenges, including substantial volume expansion during charge/discharge cycles, low electronic conductivity, and sluggish electrochemical reaction kinetics. In contrast, defect engineering offers a viable solution to these limitations. By strategically modifying crystal structures through oxygen vacancy creation, solid solution modification, and elemental doping, the sodium storage performance of SnO2 anodes can be substantially improved. This review first provides a concise introduction to the challenges facing SnO2 anodes and the limitations of conventional modification approaches. Subsequently, it systematically examines various approaches to boost the electrochemical behavior of SnO2 as an anode material. Finally, the review outlines both the potential challenges and promising prospects of employing defect engineering to enhance the performance of SnO2 as a high-efficiency anode material for sodium storage.