<p>FeS and MoS<sub>2</sub> have attracted considerable interest owing to their advantageous electrochemical characteristics as electrode materials for supercapacitors. Nonetheless, the benefits of MoS<sub>2</sub> are constrained by insufficient cycle stability and conductivity. Conversely, FeS demonstrates commendable theoretical capacity and enduring electrical conductivity, rendering it a suitable candidate for composite electrodes. The FeS/MoS<sub>2</sub> composite exhibited a sheet-like morphology, with MoS<sub>2</sub> nanopetals uniformly adhered to the surface of each FeS/MoS<sub>2</sub> sheet via the positive charge of ferric sulfide. FeS and MoS<sub>2</sub> collaborate to generate a composite electrode exhibiting superior specific capacitance (991 Fg<sup>⁻1</sup> at 1 Ag<sup>⁻1</sup>), excellent rate performance, and cyclic stability (75% retention after 10,000 cycles) at 5 Ag<sup>⁻1</sup> in 6&#xa0;M KOH. We employed an asymmetric supercapacitor (ASC) featuring activated carbon (AC) as the positive electrode and FeS/MoS<sub>2</sub> as the negative electrode. This resulted in an exceptional capacitance of 271 Fg<sup>⁻1</sup>, an energy density of 53 Wh/kg, and a power density of 585 W/kg. The enhanced specific capacitance of the FeS/MoS<sub>2</sub> electrode may be ascribed to the synergistic interaction between Fe<sup>2</sup>⁺ and Mo<sup>4</sup>⁺ combine petals-like morphology of MoS<sub>2</sub> provides a substantial surface area for the FeS nanoplates, hence improving the conductivity and raising the efficacy of the composite FeS/MoS<sub>2</sub> electrode in electrochemical capacitors. Moreover, improved cycle performance was attained, suggesting a positive prospect for energy storage&#xa0;technology.</p> Graphical abstract <p></p>

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Facile synthesis of FeS@MoS2 nanocomposite material: an advantageous electrode for high-performance supercapacitor

  • Dost Muhammad,
  • Syed Hatim Shah,
  • Samira Elaissi,
  • Nisar Ali,
  • Mohammad M. Al-Hinaai,
  • Sohail Ahmad

摘要

FeS and MoS2 have attracted considerable interest owing to their advantageous electrochemical characteristics as electrode materials for supercapacitors. Nonetheless, the benefits of MoS2 are constrained by insufficient cycle stability and conductivity. Conversely, FeS demonstrates commendable theoretical capacity and enduring electrical conductivity, rendering it a suitable candidate for composite electrodes. The FeS/MoS2 composite exhibited a sheet-like morphology, with MoS2 nanopetals uniformly adhered to the surface of each FeS/MoS2 sheet via the positive charge of ferric sulfide. FeS and MoS2 collaborate to generate a composite electrode exhibiting superior specific capacitance (991 Fg⁻1 at 1 Ag⁻1), excellent rate performance, and cyclic stability (75% retention after 10,000 cycles) at 5 Ag⁻1 in 6 M KOH. We employed an asymmetric supercapacitor (ASC) featuring activated carbon (AC) as the positive electrode and FeS/MoS2 as the negative electrode. This resulted in an exceptional capacitance of 271 Fg⁻1, an energy density of 53 Wh/kg, and a power density of 585 W/kg. The enhanced specific capacitance of the FeS/MoS2 electrode may be ascribed to the synergistic interaction between Fe2⁺ and Mo4⁺ combine petals-like morphology of MoS2 provides a substantial surface area for the FeS nanoplates, hence improving the conductivity and raising the efficacy of the composite FeS/MoS2 electrode in electrochemical capacitors. Moreover, improved cycle performance was attained, suggesting a positive prospect for energy storage technology.

Graphical abstract