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Crafting high-performance CuZnO2/g-C3N4 nanocomposites: unleashing the power of dual-functional photocatalysis and antibacterial action

  • Kavitha Thangavelu,
  • Gomathi Abimannan,
  • Ranjith Rajendran,
  • Priyadharsan Arumugam

摘要

Visible light-driven applications utilizing semiconducting metal oxide-based photocatalyst is one of the unique strategies for environmental cleanness. The photocatalytic materials were prepared by using simple hydrothermal method and materials characterization was done by analytical techniques. The CZG (1:2) nanocatalyst showed enhanced photocatalytic performance (96%) and greater kinetics reaction rate (0.0148 min−1) than the single counterparts, which revealed that the behavior enhanced the charge carrier’s separation. It is also attributed to the improved heterojunction of interfacial contact between the copper zincate and graphitic carbon nitrate (g-C3N4). Furthermore, the stability of the sample was proved after the fifth cycle of photodegradation over the Rhodamine B. The trapping experiment declared that the OH is the most responsible and dominant reactive species for degradation reaction. Based on the outcomes of the novel research, bimetallic compounds attained the established photocatalytic potential against organic pollutants. Additionally, the plausible mechanism is also discussed with the influence of scavengers. Furthermore, the diffusion well method was used to evaluate the samples’ antibacterial efficacy against Gram-positive (Staphylococcus aureus) and Gram-negative (Escherichia coli) bacteria. CuZnO2 and g-C3N4 in a 1:2 nanocomposite showed better antibacterial capabilities. The composites’ enhanced photocatalytic and antibacterial properties are mainly ascribed to the combined effect of the heterojunction that forms between g-C3N4 and CuZnO2.