<p>In plasmonic nanocavity structures crafted by multiparticle-film systems, the accurate regulation of hot spots’ intensity and location plays a pivotal role in driving the progress of plasmon-enhanced spectroscopy, ultrasensitive sensing, photovoltaics, and photocatalysis. Here, we conduct theoretical simulations on Au@SiO<sub>2</sub> multiparticle-film configurations. By stimulating plasmonic coupling effects at diverse oblique incidence angles, we can more precisely manipulate the positions of hot spots within particle-film junctions. Notably, at specific oblique incidence angles, plasmon modes with the most robust magnetic properties can be generated, peaking at a maximum value of 2.4 × 10<sup>12</sup>. Additionally, through optimizing the radius of nanospheres in heptameric objects, Fano resonance can induce the formation of super-enhanced hot spots that are in excellent alignment with the 785&#xa0;nm resonance mode. These remarkable findings present an innovative and unprecedented approach to achieving meticulous control over the optical properties and functionalities of nanostructures, opening up new frontiers for nanophotonic applications.</p>

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Precise Manipulation of Hot Spots in Multiparticle-Film Configurations Under Oblique Incidence

  • Kaixin Guo,
  • Xiao Yang,
  • Jun Han,
  • Guihua Lu,
  • Lai Wei,
  • Peng Li,
  • Min Gao

摘要

In plasmonic nanocavity structures crafted by multiparticle-film systems, the accurate regulation of hot spots’ intensity and location plays a pivotal role in driving the progress of plasmon-enhanced spectroscopy, ultrasensitive sensing, photovoltaics, and photocatalysis. Here, we conduct theoretical simulations on Au@SiO2 multiparticle-film configurations. By stimulating plasmonic coupling effects at diverse oblique incidence angles, we can more precisely manipulate the positions of hot spots within particle-film junctions. Notably, at specific oblique incidence angles, plasmon modes with the most robust magnetic properties can be generated, peaking at a maximum value of 2.4 × 1012. Additionally, through optimizing the radius of nanospheres in heptameric objects, Fano resonance can induce the formation of super-enhanced hot spots that are in excellent alignment with the 785 nm resonance mode. These remarkable findings present an innovative and unprecedented approach to achieving meticulous control over the optical properties and functionalities of nanostructures, opening up new frontiers for nanophotonic applications.