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<p>Efficient, temperature-insensitive electromagnetic attenuation materials are critical for high microwave absorption at high temperatures. This study presents SiC/TiC/SiTiOC hybrid nanofiber mats constructed using an <i>in-situ</i> synthesis method; these mats incorporate SiC/TiC as the microwave loss unit and SiTiOC as the antioxidant unit, offering an innovative approach to high-temperature microwave absorption. The introduction of high-conductivity TiC not only optimizes the dielectric constant and impedance matching of the material but also enhances its thermal cycling stability. This design ensures steady electromagnetic attenuation, enabling the hybrid nanofiber mats to maintain robust absorption performance in the X-band, even at high temperatures. At 873 K, the material demonstrates an effective absorption bandwidth of 3.6 GHz and a minimum reflection loss of −45.55 dB. Compared to single-system absorbers, such as SiC/C nanofiber materials, with a single system, the multi-component SiC/TiC/SiTiOC hybrid nanofiber mats deliver reliable absorption performance in the temperature range of 293–873 K. This study confirms that highly conductive titanium-based ceramic materials used for dielectric property regulation effectively address the challenges of poor temperature stability and limited reusability in high-temperature carbon-ceramic absorbing materials, providing valuable insights and guidance for designing efficient microwave absorbers that can operate across a wide temperature range.</p>

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In-situ synthesized SiC/TiC/SiTiOC hybrid nanofiber mats for broad-range temperature microwave absorption

  • 期刊论文

  • 发表日期：

    2025年5月14日

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  • Yashan Huo,
  • Yuetong Qian,
  • Minshan Zhao,
  • Lei Zhang,
  • Yujia Tan,
  • Zhihui He,
  • Peng Miao,
  • Fuchun Zhang,
  • Wei Cui,
  • Renchao Che

摘要

Efficient, temperature-insensitive electromagnetic attenuation materials are critical for high microwave absorption at high temperatures. This study presents SiC/TiC/SiTiOC hybrid nanofiber mats constructed using an in-situ synthesis method; these mats incorporate SiC/TiC as the microwave loss unit and SiTiOC as the antioxidant unit, offering an innovative approach to high-temperature microwave absorption. The introduction of high-conductivity TiC not only optimizes the dielectric constant and impedance matching of the material but also enhances its thermal cycling stability. This design ensures steady electromagnetic attenuation, enabling the hybrid nanofiber mats to maintain robust absorption performance in the X-band, even at high temperatures. At 873 K, the material demonstrates an effective absorption bandwidth of 3.6 GHz and a minimum reflection loss of −45.55 dB. Compared to single-system absorbers, such as SiC/C nanofiber materials, with a single system, the multi-component SiC/TiC/SiTiOC hybrid nanofiber mats deliver reliable absorption performance in the temperature range of 293–873 K. This study confirms that highly conductive titanium-based ceramic materials used for dielectric property regulation effectively address the challenges of poor temperature stability and limited reusability in high-temperature carbon-ceramic absorbing materials, providing valuable insights and guidance for designing efficient microwave absorbers that can operate across a wide temperature range.