<p>In this study, a friction piezoelectric hybrid nanogenerator (HNG) with a sponge-like structure was developed. A novel temporary solution template process was proposed to create smaller, uniformly distributed pores within the sponge structure, allowing for the complete volatilization of the porous agent without causing structural defects. The output voltage of the porous HNG structure was nearly twice that of its solid structure, demonstrating superior electrical output performance. A peak-to-peak open circuit voltage of 168 V, a short circuit current density of 36.41 µA cm⁻², and a maximum power density of 32 W m⁻² were obtained at a load resistance of 200 MΩ by periodically compressing an HNG with a dimension of 0.8 cm×0.8 cm. The generated electricity was sufficient to directly illuminate 180 tandem white LEDs and power small electronic devices. In addition, this study shows that the HNG could detect electrical signals from different parts of the human body during movement, suggesting significant potential for applications in energy harvesting and motion sensing.</p>