<p>Simultaneous removal of multiple pollutants from industrial emissions offers significant cost and space savings when upgrading air pollution control devices. Sintering processes emit complex pollutant mixtures including SO_x, NO, volatile organic compounds (VOCs), and dioxins (PCDD/Fs). This study evaluates the simultaneous removal of NO, PCDD/Fs, and toluene using three commercial V₂O₅-MoO₃/TiO₂ (VMT) selective catalytic reduction (SCR) catalysts, under simulated flue gas conditions at 220 °C. The catalysts designated Cat-1, Cat-2, and Cat-3 differed in composition, including variations in MoO₃, V₂O₅, and the addition of SiO₂ or WO₃. The effects of H₂O_(g) and SO₂ were also evaluated to assess catalyst stability and resistance to poisoning. Cat-1, with the highest MoO₃ content, achieved the best overall performance with removal efficiencies of 93.1% for PCDD/Fs, 83.3% for NO, and 84.6% for toluene. Cat-2, containing sulfur-resistant SiO₂ and WO₃, demonstrated superior NO and PCDD/Fs removal in the presence of H₂O_(g) and SO₂. Cat-3, with the highest V₂O₅ content, exhibited the highest NO conversion when H₂O_(g) and SO₂ were absent, and its performance was minimally affected by co-pollutants. This work confirms the efficacy of VMT catalysts for multipollutant control, highlighting their potential for industrial applications.</p>