The role of osmotic pressure drop in enhancing the predictive performance of dynamic models for sustainable forward osmosis water desalination
摘要
Forward osmosis (FO) has emerged as a highly attractive separation technology owing to its potential low-grade energy consumption and versatile applications. However, a significant gap remains in understanding its performance under dynamic conditions. This study investigates the dynamic performance of the FO process using NaCl and NH4HCO3 draw solutes. This study entails a well-established FO water flux model alongside dynamic molar balances to predict the dynamic profiles of key variables including water flux, salt back-diffusion, cumulative feed and permeate volumes, and concentration/dilution rates. The membrane parameters are evaluated considering the continuous decrease in concentration gradient across the membrane throughout the operating period. These parameters are calculated through a model of the specific salt back-diffusion formulated using Pyomo-AML. Model predictions were compared to experimental data over 20 h at 1-min intervals, resulting in mean absolute errors ranging from 0.13 to 3.55% for the studied variables.