Performance evaluation of hybrid electrochemical oxidation and ultraviolet light-based persulfate process for the abatement of sodium dodecyl sulfate from wastewater

The application of hybrid advanced oxidation processes (AOPs) is an efficacious way to remediate emerging contaminants from wastewater. In the present research work, a hybrid electrochemical oxidation and ultraviolet light–based persulfate activation processes (EO-UV/PS) were used to efficiently degrade sodium dodecyl sulfate (SDS) surfactant from synthetic and municipal wastewater. By operating the EO-UV/PS at optimum operating conditions at pH of 7.0, NaCl of 0.02 M, current density of 6.4 mA/cm², persulfate dose of 2.5 mM, and operating period of 180 min, about 94.5 ± 2.8% of SDS (20 mg/L) removal was achieved from synthetic wastewater. The abetment of SDS in both EO and UV/PS obeyed pseudo-first-order kinetics with a rate constant of 0.012 and 0.019 min⁻¹, respectively. Moreover, the economic analysis revealed 0.23 $ m^-3 order⁻¹ as the operating cost for degrading SDS in EO-UV/PS. The degradation pathway experimentation suggested the generation of lauric acid by-product during SDS abatement. Besides, nearly 89.3 ± 2.9% of SDS and 58.7 ± 2.4% of total organic carbon reduction was also achieved from real municipal wastewater. Phytotoxicity test on Vigna radiata affirms the non-toxic nature of the EO-UV/PS effluent.