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Photocatalytic degradation of norfloxacin antibiotics on ZnxCd(1-x)S/g-C3N4 composites in water

  • Zanen Wu,
  • Qinjun Chen,
  • Shibiao Wu

摘要

g-C3N4/ZnxCd(1-x)S composites were synthesized by a simple hydrothermal method. The composites were characterized by X-ray diffraction, UV–vis diffuse reflectance spectroscopy, infrared spectroscopy, and electron micro-projective microscopy. According to the performance of ZnxCd(1-x)S for the photocatalytic degradation of norfloxacin under visible light in water, the best stoichiometric number of x was 0.5. The best photolytic norfloxacin degradation rate of g-C3N4/ZnxCd(1-x)S composites was 89.8%, which was obtained when the dosage ratio of g-C3N4 to ZnxCd(1-x)S was 1:1. The experiment was conducted to investigate the effect of pH on the catalyst to obtain the optimal NORF degradation environment pH in the range of 7 ± 0.3; by simulating the anions that may be contained in the actual environmental water, the results showed that the catalyst has a certain effect on the degradation of NORF when the water contains NO3, Cl and HCO3. In addition, this study also obtained that the main active substances produced by the catalyst during degradation were electron–hole pairs by adding different trapping agents in the NORF removal experiments; and the catalyst was able to achieve a degradation rate of 86.1% after four cycles of the experiments, which proved that it had good stability.