Scholarlink

<p>Titanium dioxide dispersed on reduced graphene oxide mixed zirconium phosphate HKUST-1 (ZrP@HKUST-1/Ti@rGO) was synthesized and utilized for an efficient photodegradation of aqueous phenol. Modified Hummer method was adopted for the synthesis of the reduced graphene oxide (rGO) nanosheets. Titanium dioxide was dispersed and inculcated on the surface of rGO via sonothermal method. Similarly, ZrP@HKUST-1 was also synthesized by modified method and physically mixed with Ti@rGO to obtain hybrid material (ZrP@HKUST-1/Ti@rGO). Different characterization techniques such as SEM, EDX, XRD, FTIR, TGA, XANES and Zeta potential were used to investigate physicochemical features of the hybrid material. Photocatalytic performance of the hybrid material for aqueous phenol under UV environment was investigated in a photocatalytic reactor. The reaction mixture was analyzed by high performance liquid chromatography (HPLC) for phenolic remnants. The reaction conditions for the degradation of phenol (≈90%) was optimized i.e. time; 80&#xa0;min, conc; 100&#xa0;ppm, pH; 5&#xa0;ppm, cat; 0.1&#xa0;g and temp; 55 ºC. The experimental data showed best fit to first order kinetic model (R<sup>2</sup> = 0.98) with rate constant k = 0.038&#xa0;min<sup>−1</sup>. The hybrid material exhibited excellent regeneration ability with minimal loss in activity and therefore consider a potential candidate for variety of applications.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Novel Hybrid Material as a Robust Photocatalyst for Degradation of Aqueous Phenolic Contamination

  • 期刊论文

  • 发表日期：

    2026年4月24日

查看全文
  • Bushra Bostan,
  • Saima Sadiq,
  • Inam Ullah,
  • Makkah Zaman,
  • Mian Muhammad,
  • Muhammad Sadiq

摘要

Titanium dioxide dispersed on reduced graphene oxide mixed zirconium phosphate HKUST-1 (ZrP@HKUST-1/Ti@rGO) was synthesized and utilized for an efficient photodegradation of aqueous phenol. Modified Hummer method was adopted for the synthesis of the reduced graphene oxide (rGO) nanosheets. Titanium dioxide was dispersed and inculcated on the surface of rGO via sonothermal method. Similarly, ZrP@HKUST-1 was also synthesized by modified method and physically mixed with Ti@rGO to obtain hybrid material (ZrP@HKUST-1/Ti@rGO). Different characterization techniques such as SEM, EDX, XRD, FTIR, TGA, XANES and Zeta potential were used to investigate physicochemical features of the hybrid material. Photocatalytic performance of the hybrid material for aqueous phenol under UV environment was investigated in a photocatalytic reactor. The reaction mixture was analyzed by high performance liquid chromatography (HPLC) for phenolic remnants. The reaction conditions for the degradation of phenol (≈90%) was optimized i.e. time; 80 min, conc; 100 ppm, pH; 5 ppm, cat; 0.1 g and temp; 55 ºC. The experimental data showed best fit to first order kinetic model (R2 = 0.98) with rate constant k = 0.038 min−1. The hybrid material exhibited excellent regeneration ability with minimal loss in activity and therefore consider a potential candidate for variety of applications.