Factors controlling the Geochemistry of the Uruçuí-Preto River Water in the Northeastern Brazilian Cerrado during a Complete Hydrological Cycle
摘要
The agricultural expansion in the Cerrado biome is characterized by rapid human occupation and intensified economic activities associated with the conversion of native vegetation into extensive cropland for grain production. This study examines the physicochemical parameters and elemental distribution in surface waters of the Uruçuí-Preto River during the dry and rainy seasons in a watershed located within Brazil’s last agricultural frontier, where land-use intensification poses significant risks to water resources. Surface water samples were collected at 19 points along the river’s main channel over a complete hydrological year (January to December 2021). Physicochemical analyses—pH, electrical conductivity (EC), temperature, and dissolved oxygen (DO)—and the determination of Ca, Mg, P, K, Mn, Zn, Fe, and Cu were conducted to evaluate the influence of seasonality and land-use/land-cover changes. The results indicate that local climatic conditions strongly influence the concentration of these elements. Water quality in the watershed was not substantially compromised despite its proximity to agricultural areas. Canonical correlation analysis revealed that different land-use types, including croplands and pastures, were associated with several water variables, such as physicochemical parameters (pH, EC, and DO) and specific elements (e.g., Ca, P, and Zn). The study concludes that continuous water-quality monitoring is essential to mitigate the negative impacts of excessive agricultural inputs and urban pollution. Spatial and temporal variability analyses proved effective for ensuring the sustainability of water resources in the Uruçuí-Preto River watershed. Overall, the findings highlight the importance of adopting sustainable management practices to safeguard water quality in regions vulnerable to environmental degradation.