A New Approach for the Photocatalytic degradation of Malachite Green from Aqueous Solution using PANI Modified Metal-Oxide
摘要
The advantages such as low-cost, complete mineralization, energy efficiency, environmental friendliness, and reusability have enabled the metal-oxide to play a significant role in the field of wastewater treatment. The prior studies show that the modified metal-oxide nanoparticles have high degradation efficiency of organic pollutants in the presence of visible light than unmodified. The conducting polymers have garnered significant attention in modifying metal-oxide due to their enhanced visible-light absorption, synergistic band alignment, high stability and cost-effective. The modified conducting polymer-metal-oxide shows enhanced visible light absorption, improved charge separation, bandgap narrowing making it a potential photocatalytic candidate. The prime focus of my research is to develop polyaniline-modified titanium-dioxide and their novel approach for the photocatalytic degradation of Malachite green dye. Elemental composition, crystalline structure and morphology of the materials are characterised by different techniques. The results show a reduction in band gap of TiO2 from 3.2 eV to 2.5 eV after the incorporation of PANI, also a shift in absorption range from UV region to visible region. The photoluminescence intensity of TiO2 nanoparticles was found to decrease with the addition of PANI in the nanocomposite, this can be attributed to the decreased recombination of electron–hole pairs at the PANI-TiO2 interface. The photocatalytic performance of these catalyst was tested in the degradation of malachite green, after 120 min, 97% of MG was degraded with PANI-TiO2 nanocomposites under visible light was demonstrated effective pollutant degradation. Overall, the results showcased that the PANI-TiO2 nanocomposite a promising candidate for organic pollutant removal applications.
Graphical Abstract