Abstract <p>A comparative study under dry sliding conditions was conducted to evaluate the tribological properties of advanced heterophase ceramics based on Ti(C, N)–Si<sub>3</sub>N<sub>4</sub>–SiC and TaN–Si<sub>3</sub>N<sub>4</sub>, fabricated by self-propagating high-temperature synthesis (SHS) followed hot pressing (HP). For the heterophase TaN–Si<sub>3</sub>N<sub>4</sub> ceramics, the effect of a 5 and 10 wt% content of the Y<sub>3</sub>Al<sub>5</sub>O<sub>12</sub> (YAG) sintering additive on the physical, mechanical and tribological properties was investigated. The influence of sliding speed and phase composition on the tribological behavior and wearing mechanisms was analyzed via tribological “pin-on-disk” tests against an Al<sub>2</sub>O<sub>3</sub> counterbody. The predominant ceramic phases Ti(C, N) or TaN were found to exert the greatest influence on the friction and wear performance. The addition of YAG affected positively both mechanical and tribological properties. It was found that amorphous submicrofibers with a cross-sectional diameter of about 250&#xa0;nm formed in the wear spot on the surface of TaN–Si<sub>3</sub>N<sub>4</sub> at high sliding speeds, but this did not cause a noticeable decrease in coefficient of friction, that can be explained by the insufficient proportion of such fibers. Reducing the sliding speed in range 0.8–0.3&#xa0;m/s leads to a change of dominant wearing mechanism. For Ti(C, N)–Si<sub>3</sub>N<sub>4</sub>–SiC the role of intergranular fracture, followed by oxidation of wear products and segregation of the tribooxide layer increases, whereas for TaN–Si<sub>3</sub>N<sub>4</sub> a transition from the fatigue-oxidative to the abrasive wearing occurs. The obtained results demonstrate the high potential of heterophase ceramics based on transition metal nitrides and carbonitrides for dry sliding applications, due to their advantageous combination of mechanical strength and wear resistance, exceeding those of reference ceramics based on Al<sub>2</sub>O<sub>3</sub> and B<sub>4</sub>C.</p> Graphical Abstract <p></p>

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Comparative Tribological Study of Advanced Ceramics Based on Ti(C, N)–Si3N4–SiC and TaN–Si3N4 Under Dry Sliding Conditions

  • Samat K. Mukanov,
  • Mikhail I. Petrzhik,
  • Pavel A. Loginov,
  • Nataliya V. Shvyndina,
  • Evgeny I. Patsera,
  • Evgeny A. Levashov

摘要

Abstract

A comparative study under dry sliding conditions was conducted to evaluate the tribological properties of advanced heterophase ceramics based on Ti(C, N)–Si3N4–SiC and TaN–Si3N4, fabricated by self-propagating high-temperature synthesis (SHS) followed hot pressing (HP). For the heterophase TaN–Si3N4 ceramics, the effect of a 5 and 10 wt% content of the Y3Al5O12 (YAG) sintering additive on the physical, mechanical and tribological properties was investigated. The influence of sliding speed and phase composition on the tribological behavior and wearing mechanisms was analyzed via tribological “pin-on-disk” tests against an Al2O3 counterbody. The predominant ceramic phases Ti(C, N) or TaN were found to exert the greatest influence on the friction and wear performance. The addition of YAG affected positively both mechanical and tribological properties. It was found that amorphous submicrofibers with a cross-sectional diameter of about 250 nm formed in the wear spot on the surface of TaN–Si3N4 at high sliding speeds, but this did not cause a noticeable decrease in coefficient of friction, that can be explained by the insufficient proportion of such fibers. Reducing the sliding speed in range 0.8–0.3 m/s leads to a change of dominant wearing mechanism. For Ti(C, N)–Si3N4–SiC the role of intergranular fracture, followed by oxidation of wear products and segregation of the tribooxide layer increases, whereas for TaN–Si3N4 a transition from the fatigue-oxidative to the abrasive wearing occurs. The obtained results demonstrate the high potential of heterophase ceramics based on transition metal nitrides and carbonitrides for dry sliding applications, due to their advantageous combination of mechanical strength and wear resistance, exceeding those of reference ceramics based on Al2O3 and B4C.

Graphical Abstract