Eco-Responsive Z-Scheme SrFe12O19/g-C3N4 Nanostructures for Visible-Light-Driven Antibiotic and Organic Pollutants Remediation
摘要
Pharmaceutical pollutants like azithromycin and organic dyes pose significant environmental and health risks due to their persistence and toxicity. In this study, Z-scheme nanosized strontium hexaferrite (SrFe12O19)/carbon nitride (g-C3N4) composites were synthesized via the sol-gel method using metal nitrates and direct heating with melamine to enhance visible-light-driven photocatalytic degradation. Strontium hexaferrite (SHF) and SHF/CN nanocomposites with varying g-C3N4 content (10, 20, and 30 wt%) were successfully prepared and characterized. XRD confirmed the presence of M-type SrFe12O19 and g-C3N4, while TEM/SEM analysis revealed nanosized particles (~ 10–20 nm). UV-Vis DRS analysis indicated band gaps of 2.71 eV (g-C3N4), 1.8 eV (SHF), and 1.85–1.9 eV for the composites. The nanocomposites exhibited strong ferromagnetic properties, enabling easy magnetic separation. Photocatalytic efficiency was evaluated using azithromycin and dyes (Congo red (CR) and Eriochrome black T (EBT), with SHF/CN-20 showing the highest degradation efficiency. The enhanced performance is attributed to the Z-scheme heterojunction, which improves charge separation and reactive species generation. These results highlight the potential of SHF/CN composites for effective wastewater treatment.
Graphical Abstract