Vapor-Phase Carbonylation of Methanol with the Obtaining of Acetyls on Solid-Phase Catalysts: A Review
摘要
The thermodynamic and kinetic aspects of vapor-phase carbonylation of methanol are considered, in particular the effect of temperature on the equilibrium yield of products and probable routes of acetyls production. The influence of the catalyst composition on the course of the target process, the influence of hydrogen as a gas promoter on the selectivity/yield of acetyls, the peculiarities of the course of the tandem process (coupling of decomposition and carbonylation of methanol) are analyzed.