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Catalytic Properties of Carbon Dots Based Rh-Containing Nanocomposites on Si, Al, Zr Oxides in the Water Shift Reaction

  • I. B. Bychko,
  • N. V. Vlasenko,
  • G. R. Kosmambetova,
  • L. B. Kharkova,
  • O. G. Yanko,
  • V. M. Ogenko,
  • V. I. Grytsenko,
  • P. E. Strizhak

摘要

The catalytic activity of rhodium-containing nanocomposites with carbon nanodots and Si, Al and Zr oxides in high-temperature water shift reaction has been established. The role of support lies in regulation of the surface concentration of the active component (Rh) and its localization. The use of the support with a low specific surface promote the localization of the active component on the external surface that leads to the decrease of the distance between supported Rh particles, which is important for the surface migration of intermediate products of the reaction.