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<p>The pathway of the reactions of imino-λ<sup>3</sup>-iodanes PhI=NSO<sub>2</sub>R (R = CF<sub>3</sub>, 4-MeC<sub>6</sub>H<sub>4</sub>) with chalcone depends on the nature of the oxidizing agent and the solvent. The reactions with halogen-containing oxidizers afforded a wide range of derivatives, including halo amides, halo amidines, 1,2-disubstituted imidazoline, and the 1,2-diamination product, depending on the solvent (acetonitrile or dichloromethane).</p>

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Reactions of chalcone with imino-λ3-iodanes under oxidative conditions

  • 期刊论文

  • 发表日期：

    2026年2月1日

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  • A. S. Ganin,
  • M. M. Sobyanina,
  • M. Yu. Moskalik,
  • T. N. Borodina,
  • S. V. Zinchenko

摘要

The pathway of the reactions of imino-λ3-iodanes PhI=NSO2R (R = CF3, 4-MeC6H4) with chalcone depends on the nature of the oxidizing agent and the solvent. The reactions with halogen-containing oxidizers afforded a wide range of derivatives, including halo amides, halo amidines, 1,2-disubstituted imidazoline, and the 1,2-diamination product, depending on the solvent (acetonitrile or dichloromethane).