Scholarlink

<p>The review is devoted to electrosynthesis of electrically conducting polymers (ECPs) in the presence of macromolecular matrices (templates), in particular, sulfonated polyelectrolytes. Both general regularities of the process and its specific features characteristic of particular polymers are considered taking polyaniline, polypyrrole, and poly(3,4-ethylenedioxythiophene) as relevant examples. Particular attention is paid to the effect of the conformational state of the polyelectrolyte in an aqueous solution on the synthesis kinetics and on the structure and electrochemical, optical, and spectroelectrochemical properties of the resulting films of ECP—polyelectrolyte complexes. Understanding the role of the macromolecular matrix in electropolymerization and its influence on the structure and properties of the resulting ECP complexes can help in developing polymer films with predetermined functionality and improved life characteristics for applications in electrochromic, electroluminescent, and photovoltaic devices, in power sources, supercapacitors, chemical and biological sensors, <i>etc</i>.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Complexes of electrically conducting polymers with macromolecular matrices

  • 期刊论文

  • 发表日期：

    2025年11月1日

查看全文
  • O. L. Gribkova,
  • A. A. Nekrasov

摘要

The review is devoted to electrosynthesis of electrically conducting polymers (ECPs) in the presence of macromolecular matrices (templates), in particular, sulfonated polyelectrolytes. Both general regularities of the process and its specific features characteristic of particular polymers are considered taking polyaniline, polypyrrole, and poly(3,4-ethylenedioxythiophene) as relevant examples. Particular attention is paid to the effect of the conformational state of the polyelectrolyte in an aqueous solution on the synthesis kinetics and on the structure and electrochemical, optical, and spectroelectrochemical properties of the resulting films of ECP—polyelectrolyte complexes. Understanding the role of the macromolecular matrix in electropolymerization and its influence on the structure and properties of the resulting ECP complexes can help in developing polymer films with predetermined functionality and improved life characteristics for applications in electrochromic, electroluminescent, and photovoltaic devices, in power sources, supercapacitors, chemical and biological sensors, etc.