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<p>Convenient syntheses of functionalized 2-hydroxyalkyl-substituted organophosphorus acids and their derivatives based on nucleophilic addition of trimethylsilyl esters of tricoordinated phosphorus acids to functionalized oxiranes have been developed. 2-Trimethylsiloxyalkyl-substituted phosphonites are effective synthons for the production of new functionalized 2-hydroxyalkyl-substituted organophosphorus acids bearing amino, carboxy or sulfo groups. The resulting compounds are of interest as potential bioactive substances, promising extractants and polydentate ligands.</p>

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Oxirane-based synthesis of functionalized derivatives of 2-hydroxyalkyl-substituted organophosphorus acids

  • 期刊论文

  • 发表日期：

    2025年2月1日

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  • Yu. N. Bubnov,
  • A. A. Prishchenko,
  • M. V. Livantsov,
  • O. P. Novikova,
  • L. I. Livantsova,
  • S. V. Baranin

摘要

Convenient syntheses of functionalized 2-hydroxyalkyl-substituted organophosphorus acids and their derivatives based on nucleophilic addition of trimethylsilyl esters of tricoordinated phosphorus acids to functionalized oxiranes have been developed. 2-Trimethylsiloxyalkyl-substituted phosphonites are effective synthons for the production of new functionalized 2-hydroxyalkyl-substituted organophosphorus acids bearing amino, carboxy or sulfo groups. The resulting compounds are of interest as potential bioactive substances, promising extractants and polydentate ligands.