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<p>Visible light-assisted (<i>λ</i> = 465–470 nm) reactions of (phenyl)(trifluoromethylsulfonylimino)-λ<sup>3</sup>-iodane with alkenes gave products of sulfonamidation and cyclization. Solvent effect on the product composition was revealed. A comparison of the reactions of the title iodane with cyclohexene carried out in the presence of <i>N</i>-halosuccinimides and under blue LED-light-activation conditions (440–450 nm) revealed the differences in triflamidation reaction producing cyclic (aziridine) and linear (halo amides, halo amidines) products. Plausible reaction mechanisms were discussed.</p>

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Visible light-assisted reactions of (phenyl)(trifluoromethylsulfonylimino)-λ3-iodane with alkenes

  • 期刊论文

  • 发表日期：

    2025年1月1日

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  • A. S. Ganin,
  • M. Yu. Moskalik

摘要

Visible light-assisted (λ = 465–470 nm) reactions of (phenyl)(trifluoromethylsulfonylimino)-λ3-iodane with alkenes gave products of sulfonamidation and cyclization. Solvent effect on the product composition was revealed. A comparison of the reactions of the title iodane with cyclohexene carried out in the presence of N-halosuccinimides and under blue LED-light-activation conditions (440–450 nm) revealed the differences in triflamidation reaction producing cyclic (aziridine) and linear (halo amides, halo amidines) products. Plausible reaction mechanisms were discussed.