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<p>The review systematizes and summarizes information on chemical transformations of calcium carbide catalyzed by transition metals. The successful application of CaC<sub>2</sub> was demonstrated for obtaining mono- and disubstituted alkynes, a wide range of heterocyclic compounds, in particular pharmaceutically important triazoles and imidazoles. Calcium carbide is a convenient reagent for development of organic syntheses based on a carbon-neutral cycle.</p>

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Reactions of calcium carbide catalyzed by transition metals: recent advances and prospects

  • 期刊论文

  • 发表日期：

    2025年6月1日

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  • Yu. V. Gyrdymova,
  • A. N. Potorochenko

摘要

The review systematizes and summarizes information on chemical transformations of calcium carbide catalyzed by transition metals. The successful application of CaC2 was demonstrated for obtaining mono- and disubstituted alkynes, a wide range of heterocyclic compounds, in particular pharmaceutically important triazoles and imidazoles. Calcium carbide is a convenient reagent for development of organic syntheses based on a carbon-neutral cycle.