Synthesis of functionalized bis(2,2,2-trifluoroethyl) phosphonates based on tris(2,2,2-trifluoroethyl) phosphite

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发表日期：

2024年11月1日

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Yu. N. Bubnov,
A. A. Prishchenko,
M. V. Livantsov,
O. P. Novikova,
L. I. Livantsova,
S. V. Baranin

摘要

Convenient synthesis of functionalized bis(2,2,2-trifluoroethyl) phosphonates based on tris(2,2,2-trifluoroethyl) phosphite using N-chloromethylamino carboxylic acids and carbonyl compounds has been developed. The resulting compounds containing functionalized N-amidomethyl and phosphoryl moieties have potential biological activity, and are of interest as effective extractants and polydentate chelating ligands, as well as components of lithium-ion battery electrolytes.