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Synthesis of condensed dibenzo[b,f]pyrimido[1,6-d][1,4]oxazepines based on Biginelli products

  • V. L. Baklagin,
  • V. V. Bukhalin,
  • E. A. Smirnova,
  • I. G. Abramov,
  • S. I. Filimonov,
  • S. A. Ivanovsky,
  • K. Yu. Suponitsky

摘要

A method for the synthesis of substituted dibenzo[b,f]pyrimido[1,6-d][1,4]oxazepines fused with the Biginelli products was proposed. This condensation was accomplished by the aromatic nucleophilic substitution reaction between 4,5-dichlorophthalonitrile or 4-bromo-5-nitrophthalonitrile and the salicylaldehyde-based Biginelli products.