Quasi-aromatic clathrochelate-centered radicals: preparation, reactivity, and prospects for practical application
摘要
The review is devoted to the main synthetic strategies and optimal methods for preparation of persistent clathrochelate-centered radicals, the macrobicyclic products of free-radical reactions of the clathrochelate precursors. Prospects for practical applications of this type of compounds as radical polymerization initiators and paramagnetic probes for MRI and EPR studies are analyzed.