New ferrocene- and ruthenocene-based nickel pincer complexes

期刊论文
发表日期：

2024年10月1日

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S. V. Safronov,
S. A. Kuklin,
N. V. Abramova,
Yu. V. Nelyubina

摘要

First ferrocene- and ruthenocene-based nickel pincer complexes, NiCl[{2,5-(Bu^t₂PCH₂)₂C₅H₂}Fe(C₅H₅)] (3a) and NiCl[{2,5-(Bu^t₂PCH₂)₂C₅H₂}Ru(C₅H₅)] (3b), respectively, were synthesized and characterized by ¹H, ³¹P{¹H}, and ¹³C{¹H} NMR spectroscopy. The structure of complex 3b was established by single-crystal X-ray diffraction.