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Hydrolytic opening of the imidazole ring under action of acetylenecarboxylic acid derivatives

  • K. V. Belyaeva,
  • L. P. Nikitina,
  • A. V. Afonin,
  • B. A. Trofimov

摘要

A three-components regioselective synthesis of 3-[2-formamidovinyl(phenyl)amino]-acrylic acid based on an opening of the imidazole ring under the influence of acetylene carboxylic acids esters or cyanophenylacetylene in aqueous acetonitrile in up to 86% yields has been developed.