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Modified 2,3-bis(thienyl)quinoxaline fluorophores as potential chemosensors

  • T. N. Moshkina,
  • A. E. Kopotilova,
  • D. A. Gazizov,
  • M. I. Valieva,
  • E. S. Starnovskaya,
  • A. A. Kalinichev,
  • D. S. Kopchuk,
  • E. V. Nosova,
  • V. N. Charushin

摘要

2,3-Bis[5-(pyren-1-yl)thiophen-2-yl]quinoxalines and 2,3-bis{5-[4-(9H-carbazol-9-yl)phenyl]thiophen-2-yl}pyrazino[2,3-f][1,10]phenanthroline were synthesized. One- and two-photon absorption and emission of the compounds were studied, the cross sections of the two-photon absorption were found to be equal to 101–476 GM in THF. Fluorescent responses of pyrene-containing fluorophores and dipyrido-annelated quinoxaline to nitroaromatic compounds and metal cations, respectively, were investigated.